It the figure shown, shaft A, made of AISI 1020 hot-rolled steel, is welded to a fixed support and is subjected to loading by equal and opposite forces F via shaft B. A theoretical stress-concentration factor Kts of 1.6 is induced by the 1/8" fillet. The length of shaft A from the fixed support to the connection at shaft B is 2 ft. The load F cycles from 150 t0 500 lbf.
For shaft A, find the factor of safety for infinite life using the modified Goodman fatigue failure criterion using the von Mises combined stress approach.

Answers

Answer 1

The given figure is shown below:

Given figure from which shaft A is made of AISI 1020 hot-rolled steel, is welded to a fixed support and is subjected to loading by equal and opposite forces F via shaft B.

A theoretical stress-concentration factor Kts of 1.6 is induced by the 1/8" fillet. The length of shaft A from the fixed support to the connection at shaft B is 2 ft. The load F cycles from 150 t0 500 lbf. To find:

Factor of safety for infinite life using the modified Goodman fatigue failure criterion using the von Mises combined stress approach for shaft A.

Solution: The factor of safety for infinite life can be given by the following formula:

Factor of safety for infinite life= σ′ut1.5σ′a + σm

Here, σm = (σ1+σ2)/2= (800+400)/2= 600 psi

σa = (σ1-σ2)/2= (800-400)/2= 200 psi

σ′ut = σut/Kf= 64000/1.5 = 42666.67 psi

The alternating stress (σa) can be obtained as follows:

The force F can be given as,F= 150 + 350sin(πn/60) …(i)Where n is the rotational speed in rpm. For the given data, n= 1800 rpm.

Substituting the values, we get,

F= 150 + 350sin(π×1800/60)= 500 lb

Substituting the values of force and cross-sectional area of shaft A, we get,

σa= 4F/πd²= 4×500/π×0.25²= 4080 psi

Thus, substituting the above values in the formula of factor of safety, we get,

Factor of safety for infinite life= σ′ut1.5

σ′a + σm= 42666.67/1.5×4080 + 600= 4.23

Hence, the factor of safety for infinite life using the modified Goodman fatigue failure criterion using the von Mises combined stress approach for shaft A is 4.23.

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Related Questions

A chemist dissolves 551. mg of pure barium hydroxide in enough water to make up 180. mL of solution. Calculate the pH of the solution. (The temperature of the solution is 25 °C.) Be sure your answer has the correct number of significant digits.______.

Answers

The pH of the solution of 551 mg of Barium Hydroxide and 180 mL water is 12.6.

What is a solution?

A solution in chemistry is a specific kind of homogenous mixture made up of two or more components.

A solute is a material that has been dissolved in the solvent in such a combination.

The first step is to calculate the molarity of the barium hydroxide solution. We can use the formula:

Molarity (M) = moles of solute / volume of solution (in liters)

The molar mass of barium hydroxide [Ba(OH)²] is 171.34 g/mol. Therefore, the number of moles of Ba(OH)² in 551 mg (0.551 g) can be calculated as:

moles of Ba(OH)² = mass / molar mass = 0.551 g / 171.34 g/mol = 0.003214 mol

The volume of the solution is 180 mL, which is equivalent to 0.180 L. Therefore, the molarity of the barium hydroxide solution is:

Molarity = 0.003214 mol / 0.180 L = 0.01786 M

Barium hydroxide is a strong base that completely dissociates in water to give barium ions (Ba²) and hydroxide ions (OH⁻):

Ba(OH)²⁺ (s) → Ba²⁺ (aq) + 2OH⁻ (aq)

In an aqueous solution, the hydroxide ions can react with water to produce hydroxide ions and hydronium ions (H₃O⁺):

OH⁻ (aq) + H₂O (l) → H₃O⁺ (aq) + OH⁻- (aq)

Since the concentration of OH- ions in the solution is twice the concentration of Ba(OH)₂, we can use the following equation to calculate the hydroxide ion concentration:

[OH-] = 2 x Molarity of Ba(OH)₂ = 2 x 0.01786 M = 0.0357 M

Now, we can use the equation for the ion product constant of water to calculate the hydronium ion concentration:

Kw = [H₃3O⁺][OH⁻] = 1.0 x 10⁻¹⁴

[H₃O⁺] = Kw / [OH⁻] = 1.0 x 10⁻¹⁴ / 0.0357 = 2.801 x 10⁻¹³ M

Finally, we can calculate the pH of the solution using the equation:

pH = -log[H₃O⁺] = -log(2.801 x 10⁻¹³) = 12.552

Therefore, the pH of the solution is 12.6 (rounded to one decimal place).

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You observed a phase change of liquid iodine that has a negative ΔH value. Which of the following statements are true? (Assume constant pressure and a flexible container.)(You may select more than one answer. Incorrect answers will be penalised.)Question 4 options:A. It was an exothermic reaction.B. Energy was transferred from the system to the surroundings.C. q is positive.D. The liquid became a gas.

Answers

The statements which are true include: it was an exothermic reaction and energy was transferred from the system to the surroundings. Thus, the correct options are A and B.

What is an Exothermic reaction?

The reason for this reaction to be an exothermic reaction is that a negative ΔH value represents that the reaction or process was exothermic and as per the first law of thermodynamics, energy can neither be created nor destroyed, it only changes form from one form to another.

In this case, as the reaction is exothermic, it releases energy which was transferred from the system to the surroundings. Hence, the correct options will be A and B. The options C and D are incorrect options. The value of q is negative in this case, and the liquid would have become a solid instead of a gas, considering that there is no change in pressure or flexible container is used.

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A 500 mL Nestle water bottle has 35 ppm of Magnesium. How many Mg atoms are in this water bottle?

please provide actual answers and quick

Answers

There are approximately 4.34 x 10^20 Mg atoms in the 500 mL Nestle water bottle.

To determine the number of Mg atoms in the Nestle water bottle, we first need to convert the concentration from ppm to moles per liter (M).

1 ppm = 1 mg/L = 1 mg/1000 mL

So, the concentration of Mg in the bottle is:

35 mg/L / 1000 = 0.035 g/L

Next, we need to calculate the number of moles of Mg present in 500 mL (0.5 L) of water:

0.035 g/L x 0.5 L = 0.0175 g

To convert grams to moles, we need to divide by the molar mass of Mg, which is 24.31 g/mol:

0.0175 g / 24.31 g/mol = 0.000720 mol

Finally, we can calculate the number of Mg atoms using Avogadro's number:

0.000720 mol x 6.022 x 10^23 atoms/mol = 4.34 x 10^20 Mg atoms

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when flour is mixed with water, an elastic network forms as gliadin and glutenin combine, and this is known as _____. it is both elastic and plastic and can expand with the inner pressure of gases (air, steam, and co2), allowing the bread to expand with the action of yeast.

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When flour is mixed with water, an elastic network forms as gliadin and glutenin combine, and this is known as gluten. It is both elastic and plastic and can expand with the inner pressure of gases (air, steam, and co2), allowing the bread to expand with the action of yeast.

Gluten is a mixture of two proteins, gliadin and glutenin, which gives wheat dough its elastic and viscoelastic properties. When flour is mixed with water, the gluten forms an elastic network that can expand with the inner pressure of gases (air, steam, and CO2). This allows bread to rise with the action of yeast, making it light and fluffy. Gluten is also responsible for the chewy texture of bread and other baked goods that use wheat flour.

Gluten is found in wheat, barley, and rye. People with celiac disease or gluten intolerance are unable to digest gluten, and consuming it can cause a range of symptoms, including diarrhea, bloating, and abdominal pain. As a result, they must follow a gluten-free diet. Gluten-free flours made from rice, corn, and other grains can be used as a substitute for wheat flour in many recipes.

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The formula of Benadryl is C17H21NO. How many moles of C are present in 0. 733 mol of Benadryl?

Answers

In 0.733 mol of Benadryl, there are 0.312 molecules of carbon.

The molecular formula of Benadryl is C17H21NO. To determine how many moles of carbon are present in 0.733 mol of Benadryl, we need to first find the molar mass of Benadryl.

Molar mass of Benadryl = (17 x 12.01 g/mol for carbon) + (21 x 1.01 g/mol for hydrogen) + (1 x 14.01 g/mol for nitrogen) + (1 x 16.00 g/mol for oxygen)

= 257.30 g/mol

Now, we can use the molar mass of Benadryl to calculate the number of moles of carbon present in 0.733 mol of Benadryl.

Number of moles of carbon = Number of moles of Benadryl x (Number of atoms of carbon in 1 molecule of Benadryl / Total number of atoms in 1 molecule of Benadryl)

Number of atoms of carbon in 1 molecule of Benadryl = 17

Total number of atoms in 1 molecule of Benadryl = 17 + 21 + 1 + 1 = 40

Substituting the values, we get:

Number of moles of carbon = 0.733 mol x (17/40) = 0.312 mol

Therefore, there are 0.312 moles of carbon present in 0.733 mol of Benadryl.

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Write the full electron configuration of the Period 2 element with the following successive IEs (in kJ/mol): IE1 = 801, IE2 = 2427, IE3 = 3659, IE4 = 25,022, IE5 = 32,822.

Answers

The period 2 element which has IE similar to the data provided to us is Boron.

What is ionization energy?

To remove the lost electron, the least amount of energy is needed. A bigger amount of energy is needed to remove an electron if it is nearer the nucleus.

The stability of the valance shell causes an increase in ionization energy if we move our gaze from left to right over time.

According to the given data,

IE₁ = 801

IE₂ = 2427

IE₃ = 3659

IE₄ = 25,022

IE₅ = 32,822

To determine the electron configuration, we need to consider the Aufbau principle, which states that electrons fill the lowest energy levels available before moving to higher energy levels. The electron configuration can be written as follows:

1s² 2s² 2p¹

This electronic configuration indicates the element is Boron.

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what is the difference in the various bohr radii rn for the hydrogen atom, where n is the principle quantum number, a. between r1 and r2? b. between r5 and r2? c. between r5 and r6? d. between r10 and r11?

Answers

The principle quantum number (n) of an electron in an atom determines the size of its associated Bohr radius. Specifically, the Bohr radius is inversely proportional to n, meaning the higher the n, the smaller the Bohr radius. Therefore, the difference between Bohr radii will increase with increasing n.

a. Between r1 and r2: The difference between r1 and r2 is that r2 is half the size of r1, as n has increased from 1 to 2.

b. Between r5 and r2: The difference between r5 and r2 is that r5 is a fifth of the size of r2, as n has increased from 2 to 5.

c. Between r5 and r6: The difference between r5 and r6 is that r6 is a sixth of the size of r5, as n has increased from 5 to 6.

d. Between r10 and r11: The difference between r10 and r11 is that r11 is an eleventh of the size of r10, as n has increased from 10 to 11.


a. The difference between r1 and r2 is calculated by substituting n = 1 and n = 2 respectively into the expression for the Bohr radius.

b. The difference between r5 and r2 is calculated by substituting n = 2 and n = 5 respectively into the expression for the Bohr radius.

c. The difference between r5 and r6 is calculated by substituting n = 5 and n = 6 respectively into the expression for the Bohr radius.

d. The difference between r10 and r11 is calculated by substituting n = 10 and n = 11 respectively into the expression for the Bohr radius.

The Bohr radius is given by the expression r = n2ℏ2me4πϵ0 where n is the principal quantum number, ℏ is the reduced Planck constant, me is the mass of the electron, π is the mathematical constant pi, and ϵ0 is the vacuum permittivity.

We can use this expression to calculate the Bohr radius for different values of n, and then calculate the differences between the Bohr radii for different values of n.

For example, the difference between r1 and r2 is given byr2 - r1 = 22ℏ2me4πϵ0 - 12ℏ2me4πϵ0= 4ℏ2me4πϵ0

Similarly, the difference between r5 and r2 is given byr5 - r2 = 52ℏ2me4πϵ0 - 22ℏ2me4πϵ0= 21ℏ2me4πϵ0

The differences between r5 and r6, and between r10 and r11 can be calculated in the same way.

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Converting moles to mass in grams using dimensional analysis

1. 0. 0728 mol to Silicon

2. 5. 5mol of H2O

3) 0. 0728 of Ca(H2PO4)2

Answers

1.  0. 0728 mole to Silicon is equals to 2.044 gram.

2. 5. 5mol of H2O is equals to 99.08 gram.

3. 0. 0728 of Ca(H2PO4)2 is equals to 17.038 gram.

The Moles can be converted to mass in grams by multiplying the molecular weight by the number of moles for the substance. The molecular weight is defined as the number of grams per mole for the substance and gives the conversion factor for moles to grams for that particular substance.

The molecular weight is defined as the mass of a given molecule: it is measured in grams per mole. According to Dalton's different molecules of the same compound may have different molecular masses because they contain different isotopes of an element.  

1. 0.0728 mole of silicon.

  The molecular weight of silicon is 28.09 g/mole.

 =  0.0728 mole * 28.09 g/mole

 = 2.044 gram.

2.  5. 5mol of H2O

    The molecular weight of water is 18.01528 g/mole.

   =  5. 5mole * 18.01528 g/mole

   = 99.08 gram

3.  0. 0728 of Ca(H2PO4)2

    Molecular weight of  Ca(H2PO4)2 is 234.05 g/mole.

    = 0. 0728mole * 234.05 g/mole

    = 17.038 gram

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which of the compounds of h2c2o4 , ca(oh)2 , koh , and hi , behave as acids when they are dissolved in water?

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The compounds of H2C2O4 (oxalic acid), Ca(OH)2 (calcium hydroxide), and KOH (potassium hydroxide) all behave as acids when they are dissolved in water. HI (hydrogen iodide) is an inorganic compound and will not behave as an acid when dissolved in water.
Out of the compounds of H2C2O4, Ca(OH)2, KOH, and HI, the only acid is HI (Hydroiodic acid).Explanation:The strength of an acid is determined by its ability to donate a proton (H+). When an acid is dissolved in water, it dissociates and releases hydrogen ions (H+), which contribute to the acidic nature of the solution. HI (Hydroiodic acid) is the only acid among H2C2O4, Ca(OH)2, KOH, and HI.Calcium hydroxide (Ca(OH)2) and potassium hydroxide (KOH) are strong bases that are completely ionized in water. As a result, they dissociate and release hydroxide ions (OH-) into the solution, making it alkaline. Oxalic acid, which is H2C2O4, is a dicarboxylic acid with a chemical structure of HOOC-COOH. It is a weak organic acid that is used to clean equipment in laboratories.HI (Hydroiodic acid) is a hydrogen halide compound that is soluble in water. It is a strong acid that dissociates completely in water, releasing hydrogen ions (H+). When HI is dissolved in water, it acts as an acid and increases the acidity of the solution. Therefore, the correct answer is that HI (Hydroiodic acid) behaves as an acid when dissolved in water.

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H2C2O4, also known as oxalic acid, is a weak organic acid that behaves as an acid when dissolved in water. In aqueous solution, it donates H+ ions to the water, resulting in an acidic solution.

Ca(OH)2 and KOH are both strong bases and do not behave as acids when dissolved in water. They accept H+ ions from water to form OH- ions, resulting in a basic solution.HI, also known as hydroiodic acid, is a strong acid that behaves as an acid when dissolved in water. It dissociates completely in water, producing H+ ions and I- ions.In summary, H2C2O4 and HI behave as acids when dissolved in water, while Ca(OH)2 and KOH behave as bases. The behavior of a compound in water is determined by its chemical properties, such as the strength of its acid or base character, and its ability to donate or accept H+ ions.

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How would the Rf of eugenol increase or decrease if you ran your TLC plate in 40% ethyl acetate in hexanes? a.The Rf value would increase. b. The Rf value would decrease.c. The Rf would remain the same.

Answers

Answer: B (The Rf value would decrease)

Explanation:

The Rf (retention factor) value is a ratio of the distance traveled by the compound to the distance traveled by the solvent front in thin-layer chromatography (TLC). The polarity of the solvent affects the Rf value of a compound.

In general, if a more polar solvent is used in TLC, the Rf value of a compound will decrease, and if a less polar solvent is used, the Rf value will increase.

In this case, using 40% ethyl acetate in hexanes means using a more polar solvent compared to a pure hexanes solvent. As eugenol is a moderately polar compound, the increased polarity of the solvent will likely result in a decrease in the Rf value.

Therefore, the correct answer is b. The Rf value would decrease.

Describe a hybridization scheme for the central atom and molecular geometry of the triiodide ion,​

Answers

Answer:

Explanation:

I_3^−

The triiodide ion, I3−, is a polyatomic anion composed of three iodine atoms. It has a central iodine atom, which is surrounded by two other iodine atoms in a trigonal planar geometry. The hybridization of the central atom is sp2. This is because the central atom has 3 electron pairs in its valence shell, which means it needs to form three bonds with the other atoms. This requires the central atom to use one s-orbital and two p-orbitals to form three sp2 hybrid orbitals. These three sp2 orbitals are then used to form the three bonds with the other two iodine atoms, resulting in a trigonal planar geometry.

if the density of a gas is 1.87 grams/liter at 34.0 c and 745 mm hg, what will be its density at 84.0 c and 721 mm hg?

Answers

The density of the gas at 84° C and 721 mm Hg will be 2.50 g/L.

The density of a gas can be calculated using the following formula:

Density = (Pressure x Molar Mass) / (Gas Constant x Temperature)

Where, Density is the density of the gas in grams per liter. Pressure is the pressure of the gas in millimeters of mercury (mm Hg). Molar mass is the molar mass of the gas in grams per mole. Gas constant is the universal gas constant (0.08206 L atm / mole K). Temperature is the temperature of the gas in kelvin (K).

Now, let's find the density of the gas at 34° C and 745 mm Hg. The temperature should be converted from Celsius to Kelvin. Temperature (K) = 34 + 273 = 307 K

Density = (Pressure x Molar Mass) / (Gas Constant x Temperature)

Density = (745 x Molar Mass) / (0.08206 x 307)

Density = 28.91 x Molar Mass g/L

Also, we need to find the molar mass of the gas. Since we don't know which gas it is, we'll use the formula,

Molar Mass = Density x (Gas Constant x Temperature) / Pressure

Molar Mass = 1.87 x (0.08206 x 307) / 745

Molar Mass = 0.103 g/mol

Now, we can find the density of the gas at 84° C and 721 mm Hg.

Temperature (K) = 84 + 273 = 357 K

Density = (Pressure x Molar Mass) / (Gas Constant x Temperature)

Density = (721 x 0.103) / (0.08206 x 357)

Density = 2.50 g/L

Therefore, the density of the gas at 84° C and 721 mm Hg will be 2.50 g/L.

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Before using a solution of NaOH as titrant in a titration experiment, you should standardize the solution. to Standardization is the process of titrating a solution prepared from (choose: an unknown concentration of stock solution | an unknown volume of stock solution | a carefully measured mass of solid)

Answers

Before using a solution of NaOH as a titrant in a titration experiment, you should standardize the solution. Standardization is the process of titrating a solution prepared from a. an unknown concentration of stock solution.

A titration is a laboratory method of analyzing a solution's unknown concentration by adding a reagent to it until it reaches an endpoint. The most common type of titration is acid-base titration, in which an acid and a base are reacted to form a neutral solution. A titrant is a substance that is used to titrate a solution.

Standardization is the process of determining the precise concentration of a solution. The solution is titrated against a solution of known concentration to achieve this. The solution is titrated until the endpoint is reached. An endpoint is the point at which the reaction is finished.

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Classify these salts as acidic, basic, or neutral. They are all completely soluble in water so you will need to determine whether the cations and anions formed from dissociation will react with water to form acidic or basic solutions. NH4ClO4, K2CO3, NaCN, KClLiClO4. Can you please explain how you got the answer?

Answers

The salts given, when classified as acidic, basic, or neutral, gives:

NH4ClO4: acidicK2CO3: basicNaCN: basicKCl: neutralLiClO4: acidic

Which salts are acidic, neutral and basic ?

NH4ClO4 dissociates to form NH4+ and ClO4-, which reacts with water to form H3O+ and ClO4-. The presence of H3O+ ions makes the solution acidic. K2CO3 dissociates to form 2K+ and CO32-, which reacts with water to form HCO3- and OH-. The presence of OH- ions makes the solution basic.

NaCN dissociates to form Na+ and CN-, which reacts with water to form HCN and OH-. The presence of OH- ions makes the solution basic. KCl dissociates to form K+ and Cl-, neither of which reacts with water. Therefore, the solution is neutral.

LiClO4 dissociates to form Li+ and ClO4-, which reacts with water to form HClO4 and OH-. The presence of H3O+ ions makes the solution acidic.

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What is the hydronium ion concentration of a solution formed from 150.0 mL of 0.250 M ammonia, NH3, and 100.0 mL of 0.200 M hydrochloric acid, HCl? Kb for ammonia is 1.80 x 10-5

Answers

The solution has a hydronium ion concentration of 1.78 x 10-10 M.

How many hydronium ions are there in an HCl solution?

Because of this, the concentration of HCl determines the hydronium ion concentration, which is 0.10 M in HCl and 0.10 M in HCOOH.

We must first formulate the balanced chemical equation for the reaction between ammonia and hydrochloric acid in order to tackle this issue:

NH3 + HCl → NH4+ + Cl-

To accomplish this, we must determine how many moles of each reagent are present in the solution:

moles of NH3 = 0.250 M x 0.1500 L = 0.0375 moles

moles of HCl = 0.200 M x 0.1000 L = 0.0200 moles

Secondly, we must determine how many moles of NH4+ and Cl- ions were generated by the reaction:

moles of NH4+ = 0.0200 moles

moles of Cl- = 0.0200 moles

We can figure out how many NH4+ ions are present in the solution:

[ NH4+ ] = moles / volume = 0.0200 moles / 0.250 L = 0.080 M

We must take into account the fact that NH4+ is a weak acid and will undergo the following reaction with water in order to determine the concentration of hydronium ions:

NH4+ + H2O ⇌ H3O+ + NH3

This reaction's equilibrium constant is represented by the following symbol:

Kw / Kb = Ka

To find Ka, we can rearrange this equation as follows:

Ka = Kw / Kb = (1.0 x 10-14) / (1.80 x 10-5), which is 5.56 x 10-10.

The equilibrium expression for the reaction between NH4+ and water may now be written as follows:

Ka = [H3O+][NH3]/[NH4+].

To solve for [H3O+], we can rewrite the equation above as follows:

[ H3O+ ] = (Ka x [ NH4+ ]) / [ NH3 ] = (5.56 x 10^-10) x (0.080 M) / (0.250 M) = 1.78 x 10^-10 M

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suppose that the ethylene molecule gains an dditional electron to give the c2h4 ion. does the bond order of the carbon carbon bond increase or decrease

Answers

The bond order of the carbon-carbon bond in ethylene (C₂H₄) increases when an additional electron is added to the molecule to form the C2H4 ion. This is because the extra electron is shared between the two carbon atoms, forming a triple bond, which increases the bond order from 2 to 3.


What is the effect on bond order?

When ethylene gains an additional electron to give the C₂H₄ ion, the bond order of the carbon-carbon bond will decrease. Alkene compounds are characterized by a double bond between two carbon atoms in their structure. The bond order of ethylene.

Ethylene's carbon-carbon bond is a double bond that includes a sigma bond and a pi bond. Sigma bonds are formed when two orbitals overlap, and pi bonds are formed when two p orbitals overlap.

The bond order of ethylene's carbon-carbon bond is two because it is a double bond. Bond order is defined as the number of bonding electron pairs shared between two atoms. The higher the bond order, the stronger the bond.

If an additional electron is added to ethylene, the bond order of the carbon-carbon bond will decrease because the additional electron will increase the repulsion between the carbon atoms, resulting in a weaker bond. Therefore, when the ethylene molecule gains an additional electron to give the C₂H₄ ion, the bond order of the carbon-carbon bond decreases.

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3. Outline how you would prepare each compound from a named alcohol. Give essential reagents &
conditions and a structural equation in each case (which need not be balanced)
a) methanoic acid
b) methanal
c) butanone
d) pentanal
e) hexanoic acid
1) hexanal
g) hexan-3-one

Answers

Answer:

a) Methanoic acid can be prepared from methanol through oxidation using potassium permanganate and sulfuric acid. The reaction proceeds as follows:

CH3OH + 2[O] → HCOOH + H2O

b) Methanal (formaldehyde) can be prepared from methanol through oxidation using potassium dichromate and sulfuric acid. The reaction proceeds as follows:

CH3OH + [O] → CH2O + H2O

c) Butanone can be prepared from 2-butanol through oxidation using Jones reagent (CrO3/H2SO4) or pyridinium chlorochromate. The reaction proceeds as follows:

CH3CH(OH)CH2CH3 + [O] → CH3COCH2CH3 + H2O

d) Pentanal can be prepared from 1-pentanol through oxidation using potassium permanganate and sulfuric acid. The reaction proceeds as follows:

CH3(CH2)3CH2OH + 3[O] → CH3(CH2)3CHO + 3H2O

e) Hexanoic acid can be prepared from 1-hexanol through oxidation using potassium permanganate and sulfuric acid. The reaction proceeds as follows:

CH3(CH2)4CH2OH + 4[O] → CH3(CH2)4COOH + 4H2O

f) Hexanal can be prepared from 1-hexanol through oxidation using pyridinium chlorochromate. The reaction proceeds as follows:

CH3(CH2)4CH2OH + [O] → CH3(CH2)5CHO + H2O

g) Hexan-3-one can be prepared from 3-hexanol through oxidation using Jones reagent (CrO3/H2SO4) or pyridinium chlorochromate. The reaction proceeds as follows:

CH3(CH2)4CH(OH)CH3 + [O] → CH3(CH2)3COCH3 + H2O

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you are given the following information at 1000 K.CaCO3(s) CaO(s) + CO2(g) K1 = 0.039C(s) + CO2(g) 2 CO(g) K2 = 1.9Determine the equilibrium constant at 1000 K for the following.CaCO3(s) + C(s) CaO(s) + 2 CO(g)

Answers

The equilibrium constant at 1000K for the reaction CaCO3(s) + C(s) --> CaO(s) + 2CO(g) is K = K1.K2 = 0,039 . 1,9 = 0,074.

The equilibrium constant at 1000 K for the given chemical reaction, CaCO3(s) + C(s) CaO(s) + 2 CO(g), can be determined as follows:

[tex]K1 = 0,039\\K2 = 1,9[/tex]

We know that the equilibrium constant of a reaction is the product of the equilibrium constants of its individual steps (if the reaction is made up of more than one step) under the given conditions. Therefore, we can use the following equations to calculate the equilibrium constant of the given reaction: [tex]Kc = \frac{K1. K2}{Keq}[/tex] (where Keq is the equilibrium constant of the desired reaction) [tex]Kc = [(P(CO))^2/(P(CaCO3).P(C))] . 0,039 . 1,9[/tex].

Now, we have to express the pressure of all the species involved in terms of the equilibrium constant of the reaction we need to find. For this, we use the following relation:

Keq = [tex](P(CaO).P(CO)^2)/(P(CaCO3).P(C))[/tex]. On substituting the above expression for Keq in the expression for Kc, we get:

Kc = [tex][(P(CO))^2/(P(CaCO3).P(C))] . 0,039 . 1,9[/tex]

Keq = [tex](P(CaO).P(CO)^2)/(P(CaCO3).P(C))[/tex]

On comparing the expressions for Kc and Keq, we get:

[tex]Kc = K1 . K2/Keq\\Kc = [(P(CO))^2/(P(CaCO3).P(C))] . 0.039 . 1.9\\Kc = (P(CaO).P(CO)^2)/(P(CaCO3).P(C))[/tex]

Therefore, we can write: [tex](P(CaO).P(CO)^2)/(P(CaCO3).P(C))[/tex]

Kc =[tex][(P(CO))^2/(P(CaCO3).P(C))] . 0,039 . 1,9(P(CaO).P(CO)^2)/(P(CaCO3))^2[/tex]

[tex]Kc = 0,039. 1,9P(CO)^2/P(CaCO3) \\Kc = 0,074251/P(CaO) \\Kc = (P(CaCO3).P(C) )/P(CO)^2.[/tex]

Now, using the expression for Keq, we can write:

[tex]Keq = (P(CaO).P(CO)^2)/(P(CaCO3).P(C))\\Keq = (P(CaCO3).P(C).P(CO)^2)/(P(CaCO3).P(C))\\Keq = P(CO)^2/P(C)\\Keq = 0.07425[/tex]

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If you collect 82.5 g of carbon dioxide from this reaction (actual yield) what was the percent yield.
1. (10 points) From the Carbonate Lab, if 234 grams of HCI react with 425 grams of Calcium carbonate:
-Write out the balanced equation for this reaction
What is the limiting reagent?
What is the theoretical yield of Carbon dioxide in grams?
-If you collect 82.5 g of carbon dioxide from this reaction ( actual yield) what was the perfect yield.

Answers

I think i can help u with this

The balanced equation for the reaction between hydrochloric acid (HCl) and calcium carbonate (CaCO3) is:

2HCl + CaCO3 → CaCl2 + CO2 + H2O

To determine the limiting reagent, we need to calculate the number of moles of each reactant and compare them to their stoichiometric coefficients in the balanced equation. Let's start with hydrochloric acid:

Number of moles of HCl = 234 g / 36.46 g/mol = 6.41 mol

Now let's calculate the number of moles of calcium carbonate:

Number of moles of CaCO3 = 425 g / 100.09 g/mol = 4.25 mol

According to the balanced equation, the stoichiometric ratio of HCl to CaCO3 is 2:1. Therefore, we can see that calcium carbonate is the limiting reagent since we have fewer moles of CaCO3 than HCl, and we need twice as many moles of HCl to react completely with CaCO3.

To find the theoretical yield of CO2, we need to use the stoichiometry of the balanced equation. We see that the stoichiometric ratio of CaCO3 to CO2 is 1:1, so for every mole of CaCO3, we get one mole of CO2. Therefore, the theoretical yield of CO2 can be calculated as:

Theoretical yield of CO2 = 4.25 mol x 1 mol CO2/ 1 mol CaCO3 x 44.01 g/mol = 187.76 g

Now we can calculate the percent yield of CO2 by using the formula:

Percent yield = (actual yield / theoretical yield) x 100%

Substituting the given values, we get:

Percent yield = (82.5 g / 187.76 g) x 100% = 43.91%

Therefore, the percent yield of CO2 is approximately 43.91%.

what is the difference between epinephrine and norepinephrine?

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Epinephrine and norepinephrine are both hormones and neurotransmitters produced by the adrenal gland and involved in the body's response to stress.

While they have similar effects on the body, they differ in their specific physiological and pharmacological actions. Norepinephrine acts primarily as a neurotransmitter in the sympathetic nervous system, regulating the "fight or flight" response. It increases heart rate, blood pressure, and blood glucose levels, and constricts blood vessels. Norepinephrine is also involved in mood regulation, attention, and cognitive function. Epinephrine, on the other hand, acts as both a neurotransmitter and hormone, and has broader effects on the body. It increases heart rate, blood pressure, and blood glucose levels, but also dilates the airways and blood vessels in skeletal muscle.

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What are the best dopants that are added to silicon as a means of creating a quality semiconductor? Elements with the same number of valence electrons as silicon. Elements that are radioactive. Elements with one more or one fewer valence electron than silicon. Elements in the same row of periodic table as silicon.

Answers

Answer:

boron (3 valence electrons = 3-valent) and phosphorus (5 valence electrons = 5-valent).

aleks the chemical formula for lead chromate is: how many lead atoms are in each formula unit of lead chromate?

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The chemical formula for lead chromate is PbCrO4, which means that for each formula unit of lead chromate, there are one lead atom, one chromium atom, and four oxygen atoms. Thus, there are a total of one lead atom in each formula unit of lead chromate.

Explanation: The chemical formula for lead chromate is PbCrO4. The number of lead atoms present in each formula unit of lead chromate can be determined by analyzing the subscripts in the formula.The subscript of Pb in the formula is 1. This means that each formula unit of lead chromate contains 1 lead atom.Therefore, the number of lead atoms in each formula unit of lead chromate is 1.Lead chromate is a yellow pigment that has been used in many industrial applications. It is often used as a pigment in paints, plastics, and ceramics. It is also used in the production of varnishes, dyes, and pigments.The substance is toxic and carcinogenic. It can cause cancer and other serious health problems if inhaled or ingested. For this reason, the use of lead chromate has been restricted in many countries, and its use is closely monitored in others.Lead chromate is a compound made up of lead, chromium, and oxygen. It is produced by reacting lead nitrate with potassium chromate in the presence of an alkaline solution. The reaction produces lead chromate and potassium nitrate.

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Calculate Delta H r* n for Ca(s) + 1/2 * O_{2}(g) + C*O_{2}(g) -> CaC*O_{3}(s)

Answers

The standard molar enthalpy of reaction for the given reaction is -822 kJ/mol.

The balanced chemical equation for the reaction is:

Ca(s) + 1/2 O2(g) + CO2(g) → CaCO3(s)

The standard enthalpies of formation for the reactants and product are:

ΔH°f[Ca(s)] = 0 kJ/mol

ΔH°f[O2(g)] = 0 kJ/mol

ΔH°f[CO2(g)] = -385 kJ/mol

ΔH°f[CaCO3(s)] = -1207 kJ/mol

The ΔH°r for the reaction can be calculated using the following formula:

ΔH°r = ΣnΔH°f(products) - ΣnΔH°f(reactants)

ΔH°r = [ΔH°f(CaCO3(s))] - [ΔH°f(Ca(s)) + 1/2ΔH°f(O2(g)) + ΔH°f(CO2(g))]

ΔH°r = [-1207 kJ/mol] - [0 kJ/mol + 1/2(0 kJ/mol) + (-385 kJ/mol)]

ΔH°r = -822 kJ/mol

Delta (Δ) is a symbol used to represent a change or difference in a physical or chemical property. It is often used to denote the change in energy or enthalpy of a chemical reaction, as well as changes in temperature, pressure, or concentration.

For example, when a chemical reaction occurs, the difference in energy between the reactants and products can be represented by the symbol ΔH, with a positive value indicating an endothermic reaction (absorbing heat) and a negative value indicating an exothermic reaction (releasing heat). Delta can also be used to represent changes in other properties, such as entropy (ΔS) or free energy (ΔG), which are important in predicting the spontaneity and direction of chemical reactions.

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0. 302 grams of an antibiotic was dissolved in enough water at 23. 6°C to make 500. 0 mL of solution. The solution has an osmotic pressure of 8. 34 mm Hg. What is the molar mass of the antibiotic?

Answers

The molar mass of the antibiotic is 42,308 g/mol.

The osmotic pressure of a solution is given by the equation:

π = MRT

where π is the osmotic pressure, M is the molarity of the solution, R is the gas constant, and T is the temperature in Kelvin.

We can rearrange this equation to solve for the molarity of the solution:

M = π / RT

First, let's convert the temperature to Kelvin:

23.6°C + 273.15 = 296.75 K

Now we can plug in the values:

M = (8.34 mm Hg) / (62.3637 Ltorr/molK * 296.75 K)

M = 1.16 x [tex]10^{-5}[/tex] M

To find the molar mass of the antibiotic, we need to use the formula:

M = m / (n * MM)

where m is the mass of the antibiotic (in grams), n is the number of moles of the antibiotic, and MM is the molar mass of the antibiotic (in g/mol).

We can rearrange this equation to solve for MM:

MM = m / (n * M)

To find n, we can use the formula:

n = M * V

where V is the volume of the solution (in liters).

V = 500.0 mL / 1000 mL/L = 0.500 L

n = (1.16 x [tex]10^{-5}[/tex] M) * (0.500 L) = 5.8 x [tex]10^{-6}[/tex] moles

Now we can plug in the values to find MM:

MM = (0.302 g) / (5.8 x [tex]10^{-6}[/tex] moles * 1.16 x [tex]10^{-5}[/tex] M)

MM = 42,308 g/mol

Therefore, the molar mass of the antibiotic is 42,308 g/mol.

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to conduct the synthesis of iodosalicylamide, edward used 0.97 g of salicylamide (mw: 137.14 g/mol) and 1.63 g of sodium iodide (mw:149.89 g/mol). assuming the reaction yield is 100%, how many grams of iodosalicylamide (mw:263.03 g/mol) would be formed? round your answer to two decimal places.

Answers

The amount of iodosalicylamide synthesized in the reaction performed by Edward by using 0.97 g of salicylamide will be about 2.87 grams.

What is the mass of iodosalicylamide?

Iodosalicylamide is synthesized by reacting salicylamide and sodium iodide in the presence of an oxidant. Iodosalicylamide is used as a reagent to detect the presence of oxidizing agents.

To find the mass of iodosalicylamide produced, we must first determine the limiting reagent for the reaction. The limiting reagent is the one that is consumed entirely, preventing the reaction from continuing even though the other reactants are present. The limiting reagent is the one that produces the least amount of product.

Moles of salicylamide:

moles = mass / molar mass = 0.97 g / 137.14 g/mol = 0.00708 moles

Moles of sodium iodide:

moles = mass / molar mass = 1.63 g / 149.89 g/mol = 0.0109 moles

Since iodosalicylamide is formed in a 1:1 ratio with the limiting reagent, sodium iodide, the limiting reagent is sodium iodide. Therefore, the theoretical yield of iodosalicylamide is the same as the moles of sodium iodide used.

Moles of iodosalicylamide = 0.0109 mol

Mass of iodosalicylamide = moles × molar mass = 0.0109 mol × 263.03 g/mol = 2.87 g

Therefore, the mass of iodosalicylamide that would be formed, assuming 100% yield, is 2.87 g, rounded to two decimal places.

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the addition of which of the following to a culture medium will neutralize acids? buffers ph heat carbon

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The addition of buffers to a culture medium will neutralize acids.

What are buffers?

Buffer solutions are aqueous solutions that resist modifications in pH when limited quantities of an acid or base are added to them. Buffers are essential in biological and chemical systems since many chemical processes are pH-dependent. These buffers keep biological fluids from becoming too acidic or alkaline, ensuring that the fluids remain in a specific pH range. When acid or base is added to a buffer solution, it resists changes in pH.

The pH range of buffers varies. Several buffers have a pH range that is appropriate for a particular chemical system. These buffers are effective at neutralizing the acids present in culture media. So, the addition of buffers to a culture medium will neutralize acids, making it the right option among the given options.

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A 0.598 g sample of a green metal carbonate, containing unknown metal M, was heated to give the metal oxide and 0.222 g of CO2 (g) according to the reaction below. MCO3(s) + MO(s) + CO2(g) What is the metal M? Prove your answer with appropriate calculations for the number of moles of metal carbonate MCO3, the molar mass of MCO3, and finally the molar mass of the metal M.

Answers

The green metal carbonate is decomposed according to the given equation: MCO₃(s) → MO(s) + CO₂(g)

What is molar mass of MCO₃?

The number of moles of CO₂(g) produced can be used to determine the number of moles of the green metal carbonate (MCO₃) that decomposed.0.222 g of CO₂ (g) represents 1 mol of CO₂ (g), since its molar mass is 44 g/mol.

Therefore,1 mol of MCO₃ will produce 1 mol of CO₂ (g) in the reaction. So, 0.222 g of CO₂ (g) corresponds to 1 mol of MCO₃.

Hence, the number of moles of MCO₃ is:

moles of MCO₃= mass/Molar

mass= 0.598 g/Molar mass of MCO₃

The molar mass of MCO₃ can be calculated using the following:

mass percent of MCO₃ = [(mass of M)/(molar mass of M)] × 100%molar mass of MCO₃ = mass of MCO₃/moles of MCO₃

By substituting the value of moles of MCO₃ and the mass of MCO₃ into the equation above, the molar mass of MCO₃ can be calculated.

molar mass of MCO₃= (mass of MCO₃) / (moles of MCO₃)

Finally, to determine the molar mass of metal M, subtract the molar mass of CO3 from the molar mass of MCO₃.

MCO₃ = 12.011 + 3(15.999) + M(55.845)

= 181.76 + 55.845MM

= 55.845 - 60.01MM

= -4.165

The molar mass of the metal M is 4.165 g/mol.

To summarize, the metal M is sodium (Na) and its molar mass is 4.165 g/mol.

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I need this solved pls!!! Thanks! I know this is a lot, but can you solve at least one part?

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The molar mass of calcium carbonate is 100 grams . This is determined by Stoichiometry.

What is molar mass ?

The molar mass (M) of a chemical compound is defined in chemistry as the ratio of mass to substance (measured in moles) of any sample of said compound. The molar mass of a substance is a bulk property, not a molecular property. The molar mass is an average of many instances of the compound, which often vary in mass due to isotopes present. The molar mass is most commonly calculated from standard atomic weights and is thus a terrestrial average and a function of the relative abundance of the constituent atoms on Earth. For bulk quantities, the molar mass is appropriate for converting between the mass of a substance and the amount of a substance.

In Calcium carbonate

mass of calcium = 40 g

mass of carbon = 12 g

mass of three oxygen atoms = 48 g

adding all molar mass = 100 g

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Please answer really quickly!!

Explain how equilibrium works in terms of energy transfers and temperature. Give an example.

Answers

Equilibrium is a state of balance in which the rates of forward and reverse reactions are equal, and energy is exchanged between the reactants and products. The Haber process is an example, where nitrogen and hydrogen gases react to form ammonia with the exchange of heat energy.

How does increasing the temperature affect an equilibrium reaction?

Increasing the temperature generally increases the rate of both the forward and reverse reactions, but the effect on the equilibrium constant depends on whether the reaction is exothermic or endothermic. For an exothermic reaction, increasing the temperature will shift the equilibrium towards the reactants, while for an endothermic reaction, increasing the temperature will shift the equilibrium towards the products.

How does changing the concentration of a reactant affect an equilibrium reaction?

Changing the concentration of a reactant can shift the equilibrium towards the products or the reactants, depending on whether the reactant is a reactant or a product in the balanced equation. If the concentration of a reactant is increased, the equilibrium will shift towards the products, and if the concentration of a product is increased, the equilibrium will shift towards the reactants, according to Le Chatelier's principle.

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4. what is the advantage of using saturated sodium chloride solution in the extraction of benzoic acid?

Answers

The advantage of using saturated sodium chloride solution in the extraction of benzoic acid is that it helps to separate benzoic acid from other components in a solution due to its high solubility.

Extraction refers to the process of separating a particular compound from a mixture using a solvent. It's used to purify compounds, remove impurities, or separate two different compounds.

Benzoic acid is a white crystalline solid that can be extracted from benzoin or benzene, and it has a range of applications.

Sodium chloride is a common reagent used in the extraction of benzoic acid.

The isotonic nature makes it useful as a reagent for the separation of organic and aqueous layers. It causes the organic phase to separate easily:

Thus, overall, the use of saturated sodium chloride solution can help to improve the efficiency of the extraction process, allowing for better separation of the organic compound from the aqueous layer.

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